Dataframe: how to lookup values in another table, if not found, return blank/Databricks, pyspark

I'm working in Databricks to create data frame based on two existing tables. I need to look up values in 2nd table, return the value, if not found, then return blank.
for example:
df1:

df2:

I'd like to have the below df3

I used the below to add, but it join only those found in df2, so it only shows material 135 and removed Material 24, I still want to keep 1-5
df3 = df1.join(df2,["Material"]).withColumnRenamed("Material", "Material_new").drop("Material_new")
display(df3)

I'd like to have the below df3

Try with left join for this case.

Example:

df = spark.createDataFrame([(1,10),(2,50),(3,100),(4,80),(5,60)],['Material','KG'])
df1 = spark.createDataFrame([(1,1.5),(3,5.0),(5,12.0)],['Material','Conversion'])
df.join(df1,['Material'],'left').show(10,False)
#+--------+---+----------+
#|Material|KG |Conversion|
#+--------+---+----------+
#|1       |10 |1.5       |
#|2       |50 |null      |
#|3       |100|5.0       |
#|4       |80 |null      |
#|5       |60 |12.0      |
#+--------+---+----------+

Replace null with ' '

from pyspark.sql.functions import *
df = spark.createDataFrame([(1,10),(2,50),(3,100),(4,80),(5,60)],['Material','KG'])
df1 = spark.createDataFrame([(1,1.5),(3,5.0),(5,12.0)],['Material','Conversion'])
df.join(df1,['Material'],'left').\
  withColumn("conversion",when(col("conversion").isNull(),lit(" ")).\
    otherwise(col("conversion"))).\
      show(10,False)
#+--------+---+----------+
#|Material|KG |conversion|
#+--------+---+----------+
#|1       |10 |1.5       |
#|2       |50 |          |
#|3       |100|5.0       |
#|4       |80 |          |
#|5       |60 |12.0      |
#+--------+---+----------+